Substrate-induced bulk alignment of liquid crystals

Substrate-induced bulk alignment of liquid crystals.

Hard-body models of bulk liquid crystals.

Hard models for particle interactions have played a crucial role in the understanding of the structure of condensed matter. In particular, they help to explain the formation of oriented phases in liquids made of anisotropic molecules or colloidal particles and continue to be of great interest in the formulation of theories for liquids in bulk, near interfaces and in biophysical environments. Ha...

Self-alignment of liquid crystals in three-dimensional photonic crystals.

We report on the observation of self-alignment of nematic liquid crystals into colloidal photonic crystals, over distances much larger than the typical size of the voids between the spheres. We observe that the infiltrated structure possesses a unique optical axis that is determined by an intrinsic structural anisotropy of photonic crystal opals. We develop a simple model to describe this self-...

Alignment of liquid crystals on a photosensitive substrate studied by surface optical second-harmonic generation

The adsorption kinetics and orientational ordering of 4(')-n-octyl-4-cyanobiphenyl (8CB) liquid crystal films evaporated onto photosensitive poly(vinyl-cinnamate) (PVCN) substrates were investigated by surface optical second-harmonic generation. The adsorption rate of the first monolayer decreases with increasing degree of photochemical modification of the polymer. The in-plane orientational an...

Polymer-Layer-Free Alignment for Fast Switching Nematic Liquid Crystals by Multifunctional Nanostructured Substrate.

A novel polymer-layer-free system for liquid-crystal alignment is demonstrated by various shaped indium tin oxide (ITO) patterns. Liquid crystals are aligned along the ITO line pattern and secondary sputtering lithography can change the shape of the ITO line pattern. Different shapes can control the direction and size of the pretilt angle. This effect eliminates defects and reduces the response...